Input file: H:\ntc\03\Tuesday\implicit.pqi
  Output file: H:\ntc\03\Tuesday\implicit.pqo
Database file: C:\Program Files\USGS\Phreeqc Interactive 2.6\wateq4f.dat

------------------
Reading data base.
------------------

	SOLUTION_MASTER_SPECIES
	SOLUTION_SPECIES
	PHASES
	EXCHANGE_MASTER_SPECIES
	EXCHANGE_SPECIES
	SURFACE_MASTER_SPECIES
	SURFACE_SPECIES
	RATES
	END
------------------------------------
Reading input data for simulation 1.
------------------------------------

	DATABASE C:\Program Files\USGS\Phreeqc Interactive 2.6\wateq4f.dat
	SOLUTION_SPREAD
	 Description	 Temp	  pH	       O(0)	    Ca	    Mg	    Na	     K	    Cl	 S(6)	        C(4)	  N(5)	 N(-3)
	           	     	    	 O2(g) -0.7	      	      	      	      	      	     	 CO2(g) -3.5	      	      
	   Rainwater	   25	 4.5	          1	 0.384	 0.043	 0.141	 0.036	 0.236	  1.3	           1	 0.237	 0.208
	END
-------------------------------------------
Beginning of initial solution calculations.
-------------------------------------------

Initial solution 1.	 Rainwater 

-----------------------------Solution composition------------------------------

	Elements           Molality       Moles

	C(4)             1.092e-005  1.092e-005  Equilibrium with CO2(g)
	Ca               3.840e-004  3.840e-004
	Cl               2.360e-004  2.360e-004
	K                3.600e-005  3.600e-005
	Mg               4.300e-005  4.300e-005
	N(-3)            2.080e-004  2.080e-004
	N(5)             2.370e-004  2.370e-004
	Na               1.410e-004  1.410e-004
	O(0)             4.372e-004  4.372e-004  Equilibrium with O2(g)
	S(6)             1.300e-003  1.300e-003

----------------------------Description of solution----------------------------

                                       pH  =   4.500    
                                       pe  =   4.000    
                        Activity of water  =   1.000
                           Ionic strength  =  3.666e-003
                       Mass of water (kg)  =  1.000e+000
                 Total alkalinity (eq/kg)  = -3.657e-005
                       Total CO2 (mol/kg)  =  1.092e-005
                      Temperature (deg C)  =  25.000
                  Electrical balance (eq)  = -1.797e-003
 Percent error, 100*(Cat-|An|)/(Cat+|An|)  = -43.70
                               Iterations  =   8
                                  Total H  = 1.110133e+002
                                  Total O  = 5.551259e+001

---------------------------------Redox couples---------------------------------

	Redox couple             pe  Eh (volts)

	N(-3)/N(5)           9.2674      0.5482
	O(-2)/O(0)          16.1050      0.9527

----------------------------Distribution of species----------------------------

	                                           Log       Log         Log 
	Species            Molality    Activity  Molality  Activity     Gamma

	H+               3.359e-005  3.162e-005    -4.474    -4.500    -0.026
	OH-              3.380e-010  3.166e-010    -9.471    -9.500    -0.029
	H2O              5.551e+001  1.000e+000     1.744    -0.000     0.000
C(4)            1.092e-005
	CO2              1.076e-005  1.077e-005    -4.968    -4.968     0.000
	HCO3-            1.614e-007  1.514e-007    -6.792    -6.820    -0.028
	CaHCO3+          5.338e-010  4.999e-010    -9.273    -9.301    -0.029
	MgHCO3+          5.375e-011  5.034e-011   -10.270   -10.298    -0.029
	NaHCO3           1.119e-011  1.120e-011   -10.951   -10.951     0.000
	CO3-2            2.902e-013  2.246e-013   -12.537   -12.649    -0.111
	CaCO3            9.729e-014  9.738e-014   -13.012   -13.012     0.000
	MgCO3            6.083e-015  6.088e-015   -14.216   -14.216     0.000
	NaCO3-           5.871e-016  5.498e-016   -15.231   -15.260    -0.029
Ca              3.840e-004
	Ca+2             3.347e-004  2.588e-004    -3.475    -3.587    -0.112
	CaSO4            4.931e-005  4.935e-005    -4.307    -4.307     0.000
	CaHSO4+          9.764e-009  9.143e-009    -8.010    -8.039    -0.029
	CaHCO3+          5.338e-010  4.999e-010    -9.273    -9.301    -0.029
	CaOH+            1.451e-012  1.358e-012   -11.838   -11.867    -0.029
	CaCO3            9.729e-014  9.738e-014   -13.012   -13.012     0.000
Cl              2.360e-004
	Cl-              2.360e-004  2.209e-004    -3.627    -3.656    -0.029
H(0)            1.415e-020
	H2               7.073e-021  7.079e-021   -20.150   -20.150     0.000
K               3.600e-005
	K+               3.576e-005  3.347e-005    -4.447    -4.475    -0.029
	KSO4-            2.400e-007  2.247e-007    -6.620    -6.648    -0.029
Mg              4.300e-005
	Mg+2             3.664e-005  2.841e-005    -4.436    -4.546    -0.110
	MgSO4            6.360e-006  6.365e-006    -5.197    -5.196     0.000
	MgHCO3+          5.375e-011  5.034e-011   -10.270   -10.298    -0.029
	MgOH+            3.483e-012  3.262e-012   -11.458   -11.487    -0.029
	MgCO3            6.083e-015  6.088e-015   -14.216   -14.216     0.000
N(-3)           2.080e-004
	NH4+             2.055e-004  1.924e-004    -3.687    -3.716    -0.029
	NH4SO4-          2.529e-006  2.369e-006    -5.597    -5.625    -0.029
	NH3              3.465e-009  3.467e-009    -8.460    -8.460     0.000
N(5)            2.370e-004
	NO3-             2.370e-004  2.219e-004    -3.625    -3.654    -0.029
Na              1.410e-004
	Na+              1.403e-004  1.315e-004    -3.853    -3.881    -0.028
	NaSO4-           6.725e-007  6.297e-007    -6.172    -6.201    -0.029
	NaHCO3           1.119e-011  1.120e-011   -10.951   -10.951     0.000
	NaCO3-           5.871e-016  5.498e-016   -15.231   -15.260    -0.029
O(0)            4.372e-004
	O2               2.186e-004  2.188e-004    -3.660    -3.660     0.000
S(6)            1.300e-003
	SO4-2            1.238e-003  9.556e-004    -2.907    -3.020    -0.112
	CaSO4            4.931e-005  4.935e-005    -4.307    -4.307     0.000
	MgSO4            6.360e-006  6.365e-006    -5.197    -5.196     0.000
	HSO4-            3.137e-006  2.938e-006    -5.503    -5.532    -0.029
	NH4SO4-          2.529e-006  2.369e-006    -5.597    -5.625    -0.029
	NaSO4-           6.725e-007  6.297e-007    -6.172    -6.201    -0.029
	KSO4-            2.400e-007  2.247e-007    -6.620    -6.648    -0.029
	CaHSO4+          9.764e-009  9.143e-009    -8.010    -8.039    -0.029

------------------------------Saturation indices-------------------------------

	Phase               SI log IAP  log KT

	Anhydrite        -2.25   -6.61   -4.36  CaSO4
	Aragonite        -7.90  -16.24   -8.34  CaCO3
	Artinite        -22.34  -12.74    9.60  MgCO3:Mg(OH)2:3H2O
	Brucite         -12.39    4.45   16.84  Mg(OH)2
	Calcite          -7.76  -16.24   -8.48  CaCO3
	CO2(g)           -3.50  -21.65  -18.15  CO2
	Dolomite        -16.34  -33.43  -17.09  CaMg(CO3)2
	Dolomite(d)     -16.89  -33.43  -16.54  CaMg(CO3)2
	Epsomite         -5.43   -7.57   -2.14  MgSO4:7H2O
	Gypsum           -2.03   -6.61   -4.58  CaSO4:2H2O
	H2(g)           -17.00  -17.00    0.00  H2
	H2O(g)           -1.51   -0.00    1.51  H2O
	Halite           -9.12   -7.54    1.58  NaCl
	Huntite         -37.85  -67.82  -29.97  CaMg3(CO3)4
	Hydromagnesite  -55.57  -64.33   -8.76  Mg5(CO3)4(OH)2:4H2O
	Magnesite        -9.17  -17.20   -8.03  MgCO3
	Mirabilite       -9.67  -10.78   -1.11  Na2SO4:10H2O
	Nahcolite       -10.15  -21.03  -10.88  NaHCO3
	Natron          -19.10  -20.41   -1.31  Na2CO3:10H2O
	Nesquehonite    -11.57  -17.20   -5.62  MgCO3:3H2O
	NH3(g)          -10.23    0.78   11.01  NH3
	O2(g)            -0.70   -3.66   -2.96  O2
	Portlandite     -17.39    5.41   22.80  Ca(OH)2
	Thenardite      -10.60  -10.78   -0.18  Na2SO4
	Thermonatrite   -20.54  -20.41    0.13  Na2CO3:H2O
	Trona           -30.32  -41.44  -11.12  NaHCO3:Na2CO3:2H2O

------------------
End of simulation.
------------------

------------------------------------
Reading input data for simulation 2.
------------------------------------

	MIX 1
	    1    1
	END
-----------------------------------------
Beginning of batch-reaction calculations.
-----------------------------------------

Reaction step 1.

Using mix 1.	

Mixture 1.	

	 1.000e+000 Solution 1	 Rainwater                                             

-----------------------------Solution composition------------------------------

	Elements           Molality       Moles

	C                1.092e-005  1.092e-005
	Ca               3.840e-004  3.840e-004
	Cl               2.360e-004  2.360e-004
	K                3.600e-005  3.600e-005
	Mg               4.300e-005  4.300e-005
	N                4.450e-004  4.450e-004
	Na               1.410e-004  1.410e-004
	S                1.300e-003  1.300e-003

----------------------------Description of solution----------------------------

                                       pH  =   3.595      Charge balance
                                       pe  =  16.090      Adjusted to redox equilibrium
                        Activity of water  =   1.000
                           Ionic strength  =  3.680e-003
                       Mass of water (kg)  =  1.000e+000
                 Total alkalinity (eq/kg)  = -2.946e-004
                       Total CO2 (mol/kg)  =  1.092e-005
                      Temperature (deg C)  =  25.000
                  Electrical balance (eq)  = -1.797e-003
 Percent error, 100*(Cat-|An|)/(Cat+|An|)  = -43.03
                               Iterations  =  22
                                  Total H  = 1.110133e+002
                                  Total O  = 5.551259e+001

----------------------------Distribution of species----------------------------

	                                           Log       Log         Log 
	Species            Molality    Activity  Molality  Activity     Gamma

	H+               2.697e-004  2.539e-004    -3.569    -3.595    -0.026
	OH-              4.210e-011  3.942e-011   -10.376   -10.404    -0.029
	H2O              5.551e+001  1.000e+000     1.744    -0.000     0.000
C(-4)           0.000e+000
	CH4              0.000e+000  0.000e+000  -138.053  -138.052     0.000
C(4)            1.092e-005
	CO2              1.090e-005  1.091e-005    -4.963    -4.962     0.000
	HCO3-            2.037e-008  1.910e-008    -7.691    -7.719    -0.028
	CaHCO3+          6.745e-011  6.316e-011   -10.171   -10.200    -0.029
	MgHCO3+          6.796e-012  6.363e-012   -11.168   -11.196    -0.029
	NaHCO3           1.411e-012  1.412e-012   -11.850   -11.850     0.000
	CO3-2            4.562e-015  3.528e-015   -14.341   -14.452    -0.112
	CaCO3            1.531e-015  1.532e-015   -14.815   -14.815     0.000
	MgCO3            9.575e-017  9.583e-017   -16.019   -16.018     0.000
	NaCO3-           9.224e-018  8.637e-018   -17.035   -17.064    -0.029
Ca              3.840e-004
	Ca+2             3.353e-004  2.592e-004    -3.475    -3.586    -0.112
	CaSO4            4.862e-005  4.867e-005    -4.313    -4.313     0.000
	CaHSO4+          7.732e-008  7.240e-008    -7.112    -7.140    -0.029
	CaHCO3+          6.745e-011  6.316e-011   -10.171   -10.200    -0.029
	CaOH+            1.809e-013  1.694e-013   -12.743   -12.771    -0.029
	CaCO3            1.531e-015  1.532e-015   -14.815   -14.815     0.000
Cl              2.360e-004
	Cl-              2.360e-004  2.208e-004    -3.627    -3.656    -0.029
H(0)            0.000e+000
	H2               0.000e+000  0.000e+000   -42.520   -42.520     0.000
K               3.600e-005
	K+               3.576e-005  3.347e-005    -4.447    -4.475    -0.029
	KSO4-            2.363e-007  2.213e-007    -6.627    -6.655    -0.029
Mg              4.300e-005
	Mg+2             3.673e-005  2.847e-005    -4.435    -4.546    -0.111
	MgSO4            6.274e-006  6.279e-006    -5.202    -5.202     0.000
	MgHCO3+          6.796e-012  6.363e-012   -11.168   -11.196    -0.029
	MgOH+            4.346e-013  4.070e-013   -12.362   -12.390    -0.029
	MgCO3            9.575e-017  9.583e-017   -16.019   -16.018     0.000
N(-3)           0.000e+000
	NH4+             0.000e+000  0.000e+000   -49.136   -49.164    -0.029
	NH4SO4-          0.000e+000  0.000e+000   -51.052   -51.081    -0.029
	NH3              0.000e+000  0.000e+000   -54.814   -54.813     0.000
N(0)            1.580e-004
	N2               7.898e-005  7.905e-005    -4.102    -4.102     0.000
N(3)            4.548e-015
	NO2-             4.548e-015  4.259e-015   -14.342   -14.371    -0.029
N(5)            2.870e-004
	NO3-             2.870e-004  2.688e-004    -3.542    -3.571    -0.029
Na              1.410e-004
	Na+              1.403e-004  1.315e-004    -3.853    -3.881    -0.028
	NaSO4-           6.622e-007  6.200e-007    -6.179    -6.208    -0.029
	NaHCO3           1.411e-012  1.412e-012   -11.850   -11.850     0.000
	NaCO3-           9.224e-018  8.637e-018   -17.035   -17.064    -0.029
O(0)            9.137e-008
	O2               4.568e-008  4.572e-008    -7.340    -7.340     0.000
S(-2)           0.000e+000
	H2S              0.000e+000  0.000e+000  -127.054  -127.053     0.000
	HS-              0.000e+000  0.000e+000  -130.371  -130.400    -0.029
	S5-2             0.000e+000  0.000e+000  -136.300  -136.399    -0.100
	S4-2             0.000e+000  0.000e+000  -136.530  -136.633    -0.103
	S6-2             0.000e+000  0.000e+000  -136.589  -136.685    -0.097
	S-2              0.000e+000  0.000e+000  -139.608  -139.722    -0.114
	S3-2             0.000e+000  0.000e+000  -139.980  -140.086    -0.107
	S2-2             0.000e+000  0.000e+000  -141.223  -141.332    -0.109
S(6)            1.300e-003
	SO4-2            1.219e-003  9.410e-004    -2.914    -3.026    -0.113
	CaSO4            4.862e-005  4.867e-005    -4.313    -4.313     0.000
	HSO4-            2.481e-005  2.323e-005    -4.605    -4.634    -0.029
	MgSO4            6.274e-006  6.279e-006    -5.202    -5.202     0.000
	NaSO4-           6.622e-007  6.200e-007    -6.179    -6.208    -0.029
	KSO4-            2.363e-007  2.213e-007    -6.627    -6.655    -0.029
	CaHSO4+          7.732e-008  7.240e-008    -7.112    -7.140    -0.029
	NH4SO4-          0.000e+000  0.000e+000   -51.052   -51.081    -0.029

------------------------------Saturation indices-------------------------------

	Phase               SI log IAP  log KT

	Anhydrite        -2.25   -6.61   -4.36  CaSO4
	Aragonite        -9.70  -18.04   -8.34  CaCO3
	Artinite        -25.95  -16.35    9.60  MgCO3:Mg(OH)2:3H2O
	Brucite         -14.20    2.64   16.84  Mg(OH)2
	Calcite          -9.56  -18.04   -8.48  CaCO3
	CH4(g)         -135.19 -179.12  -43.93  CH4
	CO2(g)           -3.49  -21.64  -18.15  CO2
	Dolomite        -19.95  -37.04  -17.09  CaMg(CO3)2
	Dolomite(d)     -20.50  -37.04  -16.54  CaMg(CO3)2
	Epsomite         -5.43   -7.57   -2.14  MgSO4:7H2O
	Gypsum           -2.03   -6.61   -4.58  CaSO4:2H2O
	H2(g)           -39.37  -39.37    0.00  H2
	H2O(g)           -1.51   -0.00    1.51  H2O
	H2S(g)         -126.06 -167.70  -41.64  H2S
	Halite           -9.12   -7.54    1.58  NaCl
	Huntite         -45.07  -75.03  -29.97  CaMg3(CO3)4
	Hydromagnesite  -64.59  -73.35   -8.76  Mg5(CO3)4(OH)2:4H2O
	Magnesite       -10.97  -19.00   -8.03  MgCO3
	Mirabilite       -9.67  -10.79   -1.11  Na2SO4:10H2O
	N2(g)            -0.84   -4.10   -3.26  N2
	Nahcolite       -11.05  -21.93  -10.88  NaHCO3
	Natron          -20.90  -22.22   -1.31  Na2CO3:10H2O
	Nesquehonite    -13.38  -19.00   -5.62  MgCO3:3H2O
	NH3(g)          -56.58  -61.11   -4.52  NH3
	O2(g)            -4.38   78.74   83.12  O2
	Portlandite     -19.20    3.60   22.80  Ca(OH)2
	Sulfur          -92.52 -128.33  -35.81  S
	Thenardite      -10.61  -10.79   -0.18  Na2SO4
	Thermonatrite   -22.34  -22.21    0.13  Na2CO3:H2O
	Trona           -33.02  -44.14  -11.12  NaHCO3:Na2CO3:2H2O

------------------
End of simulation.
------------------

------------------------------------
Reading input data for simulation 3.
------------------------------------

-----------
End of run.
-----------